Imodium cannot produce a high as it doesn't cross the blood brain barrier. Because it has the same effect on the intestinal system as regular opiates though, it's often used during withdrawal so that they don't shit their bowels out. It's essentially delaying the start of that symptom though, it means you don't have to deal with all withdrawal effects at the same time, but eventually you're going to stop the Imodium and your ass is gonna spray like a fountain.
Overdoses of Imodium are probably directly linked to using it during withdrawal to combat the symptoms of opiod dependency. Again, it does not cross the blood brain barrier, and can't get you high. Circumventing this would involve either disabling the blood brain barrier, which would require a lot of prescription only drugs and would be very dangerous because everything you took would wind up in your brain. Or chemistry to transform it into another chemical which is complex enough that it would be far easier to just go out and buy heroin.
"Do not think that I came to bring peace... I did not come to bring peace, but a sword." - Matthew 10:34
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