Global Warming violates the 1st LoT by claiming a magical creation of thermal energy out of nothing, in the form of a temperature increase, which is somehow caused by a magical substance. Greenhouse Effect violates Stefan-Boltzmann and black body science by claiming that an increase in earth's temperature is somehow caused by a decrease in earth's radiance. Greenhouse Effect violates the 2nd LoT by claiming that the cooler atmosphere somehow heats the warmer earth's surface.